Highly phosphorescent supramolecular hydrogels based on platinum emitters.

نویسندگان

  • Naveen Kumar Allampally
  • Michael Bredol
  • Cristian A Strassert
  • Luisa De Cola
چکیده

We have synthesised a neutral, water-soluble, Pt(II) complex able to aggregate more efficiently in aqueous solutions than in organic solvents. The aggregates are luminescent and are not quenched by molecular oxygen. Further, we have prepared phosphorescent hydrogels utilising host-guest interactions between cyclodextrins and the tetraethylene glycol tails of the Pt(II) complex. The soft assemblies feature host-dependent emission properties.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Correction: Theoretical study and design of multifunctional phosphorescent platinum(ii) complexes containing triarylboron moieties for efficient OLED emitters.

Correction for 'Theoretical study and design of multifunctional phosphorescent platinum(ii) complexes containing triarylboron moieties for efficient OLED emitters' by Yong Wu et al., Phys. Chem. Chem. Phys., 2015, DOI: .

متن کامل

Blue phosphorescent emitters: new N-heterocyclic platinum(II) tetracarbene complexes.

Photoluminescence measurements show that platinum(II) tetracarbene complexes, which could be obtained via different synthetic routes, are interesting lead structures for the development of blue emitters for PhOLEDs with good quantum yields and high photostability.

متن کامل

Developing strongly luminescent platinum(IV) complexes: facile synthesis of bis-cyclometalated neutral emitters.

A straightforward, one-pot procedure has been developed for the synthesis of bis-cyclometalated chloro(methyl)platinum(IV) complexes with a wide variety of heteroaromatic ligands of the 2-arylpyridine type. The new compounds exhibit phosphorescent emissions in the blue to orange colour range and represent the most efficient Pt(IV) emitters reported to date, with quantum yields up to 0.81 in flu...

متن کامل

Trifunctional Ir(III) ppy-type asymmetric phosphorescent emitters with ambipolar features for highly efficient electroluminescent devices.

Simple trifunctional Ir(III) ppy-type asymmetric phosphorescent emitters with ambipolar character are reported, which afford highly efficient OLEDs.

متن کامل

Near infrared light-responsive and injectable supramolecular hydrogels for on-demand drug delivery.

A near infrared (NIR) light-responsive supramolecular hydrogel consisting of α-cyclodextrin and poly(ethylene glycol)-modified dendrimer-encapsulated platinum nanoparticles was developed. Upon NIR irradiation, this hydrogel underwent a photothermo-sensitive degradation to release the entrapped therapeutic agents in an on-demand and dose-tunable fashion.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemistry

دوره 20 51  شماره 

صفحات  -

تاریخ انتشار 2014